The pentacyanonitrosylferrate ion. Part 2. Reactions with various carbanions
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 1,p. 7-9
- https://doi.org/10.1039/p29860000007
Abstract
The carbanions of malononitrile, ethylmalononitrile, and dimethyl malonate react with pentacyanonitrosylferrate (nitroprusside) to form highly coloured adducts. A kinetic study has shown that, in the second and third cases, there is rate-determining reaction between carbanion and nitroprusside but, in the first, the product is that formed by a second ionisation to give [Fe(CN)5N(O)C(CN)2]4–.Keywords
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