Ligand reorganization energies as a basis for the design of synergistic metal ion extraction systems
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 13,p. 1177-1178
- https://doi.org/10.1039/a902842k
Abstract
In the extraction of alkaline earth cations by acidic organophosphorus extractants, a correlation has been demonstrated between the effectiveness of the stereoisomers of dicyclohexano-18-crown-6 as synergists and the strain energy associated with conversion of the unbound crown ether to its complexed form.Keywords
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