Crystalline molecular alloysDedicated to J.-M. Lehn on the occasion of his 65th birthday.

Abstract
The dicationic tecton 1–2H+ leads in the presence of anionic M(CN)6 3− complexes to two almost identical crystalline systems A (M = Fe) and B (M = Co) composed of 2-D H-bonded networks and water molecules. The epitaxial growth of B on A used as seed or A on B generates crystalline molecular alloys.

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