Synthesis, characterization, and catalytic activity of beidellite–montmorillonite layered sillcates and their pillared analogues

Abstract
A Synthetic beidellite-smectite, characterized by a range of techniques, including high-resolution 27Al ans 29Si solid-state n.m.r. spectroscopy, shows interesting catalytic activity (in secondary amine formation from cyclohexylamine, in ester production from hex-1-ene and acetic acid, and in ether synthesis from pentanol): the selectivities differ significantly from those of montmorillonite-smectites.

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