New analysis of the (0,0) band of the 2Π → 2Σ transition of TiN

Abstract
From new spectra and by the use of a better computation procedure it has been possible to improve the rotational analysis of the (0,0) band of the red system of TiN. In particular, the spin doubling of the lower 2Σ state has been resolved and two new perturbations have been identified in the 2Π state. The inclusion of high values of J yields more accurate molecular constants.

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