On the Mavroyannis–Stephen relativistic long‐range interaction energy term between optically active molecules
- 1 July 1971
- journal article
- Published by Wiley in International Journal of Quantum Chemistry
- Vol. 5 (4) , 469-473
- https://doi.org/10.1002/qua.560050409
Abstract
The relativistic long‐range intermolecular interaction energy term of Mavroyannis and Stephen is estimated for some amino acids by using optical rotatory dispersion data and for hexahelicene by using theoretical values of excitation energies and rotational strengths. The result shows that the interaction energy may be significant for the interaction between some essentially dissymmetric chromophores such as hexahelicene, but that it is unimportant for other cases.Keywords
This publication has 7 references indexed in Scilit:
- Relativistic Long-Range Interactions between Atoms and MoleculesThe Journal of Chemical Physics, 1970
- Optical ActivityAnnual Review of Physical Chemistry, 1969
- Long‐range interactions between atoms and moleculesInternational Journal of Quantum Chemistry, 1967
- The Nature of Intermolecular ForcesAdvances in Chemical Physics, 1967
- Dispersion forcesMolecular Physics, 1962
- Some applications of the kronig-kramers theorem to optical activityTetrahedron, 1961
- Studies on Diastereoisomeric α-Amino Acids and Corresponding α-Hydroxy Acids. IV. Rotatory Dispersion of the Asymmetric α- and ι-Carbon Atoms of Several Diastereoisomeric Amino AcidsJournal of the American Chemical Society, 1955