Elastic constants and their pressure dependences in Cd1xMnxTe with 0≤x≤0.52 and in Cd0.52Zn0.48Te

Abstract
We have measured ultrasonic transit times to determine the elastic constants of Cd1x MnxTe crystals with 0≤x≤0.52 and of Cd0.52 Zn0.48Te at 296 K using hydrostatic pressures up to 4 kbar. It is found that Mn, but not Zn, weakens the zinc-blende crystal structure and makes it less stable under pressure. Applying a modified Born criterion to our data, we deduce the pressure expected to cause the transition to the rocksalt structure in each compound. The influence of Mn we attribute to Mn 3d orbitals hybridizing into the tetrahedral bonds.