closo–nido-Cluster isomerism in metallacarbaboranes via a change of metal valency state: molecular structure of µ-1,2-acetato-2-hydrido-2,10-bis(triphenylphosphine)-closo-1,2-carbairidadecaborane
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 83-84
- https://doi.org/10.1039/c39830000083
Abstract
The iridium(III)closo-cluster structure of [µ-1,2-(MeCO·O)-2-H-2,10-(PPh3)2-closo-1,2-ClrB8H7], which also contains a novel acetate bridge, contrasts with the otherwise ostensibly isoelectronic iridium (V)iso-nido-cluster structure of [(PPh3)(Ph2P[graphic omitted]H6(OMe)C(OH)}]Keywords
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