Intramolecular [2 + 2] photoaddition of a 1,7-diene
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 11,p. 1473-1480
- https://doi.org/10.1039/p29810001473
Abstract
Intramolecular photoaddition of the 1,7-diene system in 4-(1,5-dimethylhex-4-enyl)cyclohex-2-enone (3) yielded, inter alia, two ketones containing the tricyclo[5.3.1.05,11]undecan-8-one system. The structure and stereochemistry of these ketones has been determined from X-ray crystallographic analyses of suitable derivatives.Keywords
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