Coenzyme models. Part 35. Charge separation on the micelle surface as a strategy to prove the multi-step reaction mechanism in NADH model reductions
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 9,p. 1533-1540
- https://doi.org/10.1039/p29830001533
Abstract
We have found that (i) the reaction of NADH model compounds with potassium persulphate (PPS) in anionic and non-ionic micelles initiates radical polymerisation of acrylamide and (ii) that reductive desulphonation of 2,4,6-trinitrobenzenesulphonate and 4-carboxy-2,6-dinitrobenzenesulphonate by NADH model compounds in deuterium oxide in the presence of the micelles gives 1,3,5-trinitrobenzene and 3,5-dinitrobenzoic acid, respectively, which contain 3–16% deuterium. The results indicate that the reactions proceed through multi-step hydrogen transfer via radical ion-pair intermediates and the micelle is capable of dissociating the radical ion-pairs.Keywords
This publication has 0 references indexed in Scilit: