Static distortion of 2 E g cyclohexne cation redicals giving the 2 A g state with C2h symmetry and their dynamic processes in low-temperature solids: matrix effects
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 143-145
- https://doi.org/10.1039/c39840000143
Abstract
E.s.r. evidence has been obtained showing that the jahn –Teller active radical cation of cyclo-C6H12 exhibits static distortion to the 2Ag ground state with C2h symmetry in low-temperature solids regardless of the matrix used; non-isotropic perturbation by the matrix results in a nonequivalent dynamic process in the Jahn–Teller potential surface which has three minima.Keywords
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