Synthesis and magnetism of mixed valency [N(n-C4H9)4 or P(C6H5)4]Cr II Cr III (C2O4)3
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 1513-1514
- https://doi.org/10.1039/c39950001513
Abstract
Mixed valency compounds ACrIICrIII(C2O4)3[A = N(n-C4H9)4, P(C6H5)4] have been synthesised and characterised structurally and magnetically, the structures consisting of hexagonal layers of Cr bridged by C2O42–; although short range antiferromagnetic correlations are observed below 100 K no transition to a long range ordered state is observed above 2 K.Keywords
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