Acyl-und Alkylidenphosphane, XV 2.2-Dimethylpropylidinphosphan, eine stabile Verbindung mit einem Phosphoratom der Koordinationszahl 1/ Acyl- and Alkylidenephosphines, XV 2,2-Dimethylpropvlidynephosphine, a Stable Compound with a Phosphorus Atom of Coordination Number 1
Open Access
- 1 January 1981
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 36 (1) , 16-19
- https://doi.org/10.1515/znb-1981-0105
Abstract
In the presence of small amounts of solid sodium hydroxide, [2,2-dimethyl-l-(trimethylsiloxy)propylidene]-trimethylsilylphosphine reacts at + 20 °C to give hexamethyldisiloxane and 2,2-dimethylpropylidynephosphine (2). In contrast to similar alkylidynephosphines this compound is stable at room temperature. The IR and mass spectrum are discussed, and 1H, 13C and 31P NMR spectral data are given.Keywords
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