Ferrous rather than ferric species are the active sites in bis(imino)pyridine iron ethylene polymerization catalysts

This publication has 15 references indexed in Scilit:

• Advances in Non-Metallocene Olefin Polymerization Catalysis
  Chemical Reviews, 2002
• Propylene polymerization with a bisiminepyridine iron complex: activation with Ph3C [B(C6F5)4] and AlR3; iron hydride species in the catalytic cycle
  Journal of Molecular Catalysis A: Chemical, 2002
• The nature of the active site in bis(imino)pyridine iron ethylene polymerisation catalysts
  Catalysis Communications, 2002
• Polymerization of Ethylene Catalyzed by Iron Complex Bearing 2,6-Bis(imine)pyridyl Ligand: 1H and 2H NMR Monitoring of Ferrous Species Formed via Catalyst Activation with AlMe3, MAO, AlMe3/B(C6F5)3 and AlMe3/CPh3(C6F5)4
  Macromolecular Chemistry and Physics, 2001
• Theoretical Study on Bis(imino)pyridyl−Fe(II) Olefin Poly- and Oligomerization Catalysts. Dominance of Different Spin States in Propagation and β-Hydride Transfer Pathways
  Organometallics, 2001
• Olefin Polymerization by Late Transition Metal Complexes-A Root of Ziegler Catalysts Gains New Ground
  Angewandte Chemie International Edition in English, 2001
• Late-Metal Catalysts for Ethylene Homo- and Copolymerization
  Chemical Reviews, 2000
• Mechanistic Aspects of Ethylene Polymerization by Iron(II)−Bisimine Pyridine Catalysts: A Combined Density Functional Theory and Molecular Mechanics Study
  Journal of the American Chemical Society, 1999
• The Search for New-Generation Olefin Polymerization Catalysts: Life beyond Metallocenes
  Angewandte Chemie International Edition in English, 1999
• Highly active ethylene polymerisation catalysts based on iron: an ab initio study
  Chemical Communications, 1999