Infrared laser multiple-photon dissociation of CDCl3 in a molecular beam
- 15 August 1983
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 79 (4) , 1789-1794
- https://doi.org/10.1063/1.446024
Abstract
Pulsed CO2 laser multiple‐photon dissociation of CDCl3 was examined in a molecular beam using 11 μ radiation. The only observed dissociation channel was hydrogen chloride elimination (≳99.1%), with no evidence of simple chlorine atom cleavage (<0.9%). Implications for isotope separation are discussed.Keywords
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