Aspects of catalysis. Part VI. Oxidations of sulphoxides and dioxan by dioxygen
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 607-608
- https://doi.org/10.1039/p19740000607
Abstract
Some sulphoxides are oxidised to sulphones when treated with dioxygen in aqueous propan-2-ol in the presence of soluble iridium or rhodium catalysts. A catalyst derived from rhodium acetate and lithium chloride effects a reaction between dioxan and dioxygen to give a mixture of the di- and mono-formates of ethane-1,2-diol.Keywords
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