Coriolis resonance in the v 2 0 + v 6 ±1,v 5 ∓1 + v 6 ∓1 infra-red bands of methyl chloride
- 1 July 1975
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 30 (1) , 73-79
- https://doi.org/10.1080/00268977500101771
Abstract
The v 2 0 + v 6 ±1 and v 5 ∓1 + v 6 ∓1 perpendicular bands of methyl chloride have been studied under high resolution, and found to be coupled by a strong xy Coriolis interaction, with eventual level crossing. Evidence is given for the K numbering of the branches and earlier assignments for v 5 ∓1 + v 6 ∓1 [1] are corrected. Several minor perturbations and unassigned lines remain to be clarified.Keywords
This publication has 8 references indexed in Scilit:
- Fine structure in the ν1 band of CH3Cl near 2970 cm−1Journal of Molecular Spectroscopy, 1969
- Vibration—rotation bands of methyl chlorideSpectrochimica Acta, 1966
- Vibration—rotation bands of methyl bromideSpectrochimica Acta, 1966
- Coriolis interactions about X-Y axes in symmetric topsJournal of Molecular Spectroscopy, 1966
- Vibration-Rotation Spectra, the Coriolis Coupling Constants and the Intramolecular Fore Field of Symmetric Top Molecules. II. Analysis of the Overtones and Combination Tones of Methyl BromideBulletin of the Chemical Society of Japan, 1965
- The infrared spectrum of methyl chlorideJournal of Molecular Spectroscopy, 1964
- Millimeter Wave Spectra and Centrifugal Stretching Constants of the Methyl HalidesThe Journal of Chemical Physics, 1954
- Variation in the Quadrupole Coupling Constant with Vibrational State in the Methyl HalidesThe Journal of Chemical Physics, 1954