Palladium-Complex-Catalyzed Decarboxylation-Carbonylation of Allyl Diethylcarbamates
- 1 January 1992
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1992 (04) , 323-324
- https://doi.org/10.1055/s-1992-22000
Abstract
Diethylcarbamic acid allylic esters 1 undergo decarboxylation-carbonylation to give the corresponding β,γ-unsaturated amides 2 under rather forcing conditions [CO (50-80 atm) at 100 °C] in the presence of a palladium (0)-triphenylphosphine complex as catalyst.Keywords
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