Reversible Addition of Water to the High-Hydride-Content Cluster [Rh6(PiPr3)6H12][BArF4]2. Synthesis and Structure of [Rh6(PiPr3)6H11(OH)][BArF4]2
- 9 January 2008
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 47 (3) , 778-780
- https://doi.org/10.1021/ic702195b
Abstract
The hydroxyhydrido salt [Rh6(PiPr3)6H11(OH)][BArF4]2 results from the addition of water to [Rh6(PiPr3)6H12][BArF4]2. This reaction is reversible, and the addition of dihydrogen to [Rh6(PiPr3)6H11(OH)][BArF4]2 results in the elimination of water and the regeneration of the hydride cluster.Keywords
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