Strategies for Hydrogen Storage in Metal–Organic Frameworks
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Open Access
- 18 July 2005
- journal article
- review article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 44 (30) , 4670-4679
- https://doi.org/10.1002/anie.200462786
Abstract
Increased attention is being focused on metal–organic frameworks as candidates for hydrogen storage materials. This is a result of their many favorable attributes, such as high porosity, reproducible and facile syntheses, amenability to scale‐up, and chemical modification for targeting desired properties. A discussion of several strategies aimed at improving hydrogen uptake in these materials is presented. These strategies include the optimization of pore size and adsorption energy by linker modification, impregnation, catenation, and the inclusion of open metal sites and lighter metals.Keywords
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