Studies of Organometallic Compounds XVI. The Crystal Structure of Di‐μ‐ethoxy‐bis(dibenzylethoxy‐titanium(IV))
- 1 January 1975
- journal article
- research article
- Published by Wiley in Helvetica Chimica Acta
- Vol. 58 (2) , 373-377
- https://doi.org/10.1002/hlca.19750580206
Abstract
The crystal structure of di‐μ‐ethoxy‐bis(dibenzylethoxy‐titanium(IV)), [(EtO)2Ti‐(CH2Ph)2]2, has been determined from analysis of photographic X‐ray data. The crystal system is monoclinic, a = 7.93(2), b = 15.99(2), c = 13.40(2) Å, β = 92.7(3)°, space group P21/c. The molecule is a dimer situated about a crystallographic center of symmetry. The two Ti atoms are joined by oxygen bridges. Each Ti atom is penta‐coordinated in the form of a distorted trigonal bipyramid.Keywords
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