Isomerization of diastereoisomeric alkene complexes of the formula [(η5-C5H5)Re(NO)(PPh3)(H2CCHR)]+; the alkene enantioface bound to the metal can ‘flip’ without alkene dissociation
- 1 January 1990
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 902-903
- https://doi.org/10.1039/c39900000902
Abstract
Deuterium labelling experiments show that the title reaction is intramolecular, and does not proceed by rotation of the CHR terminus; a mechanism involving a C-H ‘σ bond complex’ is proposed.Keywords
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