Correlation Functions for the Distribution Coefficients of U(IV) and Pu(III) Ions between Aqueous Nitric Acid and 30% TBP in an Aliphatic Diluent

Publisher Website
Google Scholar
Abstract
Distribution coefficient correlations for U(IV) and Pu(III) are obtained in terms of a modified form of the total nitrate ion salting strength that was successfully used to obtain distribution coefficient correlations for U(VI) and Pu(IV) in the earlier work of G. L. Richardson. The modification of salting strength was needed to account for the fact that the U(IV) distribution coefficients measured under conditions where U(VI) is present consistently fall below those obtained when it is absent. The correlations were incorporated into the mixer-settler computer model PUBG, and in the simulation of a 20-stage IB partitioning contactor, calculated product stream concentrations were in excellent agreement with experiment. Earlier mixersettler computer models, which failed to account for U(IV) distribution coefficients, predicted that U(IV) remained in the aqueous product stream, which is contrary to the experimental measurements.

This publication has 13 references indexed in Scilit: