An n.m.r. study of FeH(dmpe)2(BH4)[dmpe = 1,2-bis(dimethylphosphino)ethane]–an iron complex containing amonodentate borohydrid ligand
- 1 January 1984
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 996-997
- https://doi.org/10.1039/c39840000996
Abstract
The single-hydrogen bridge attachment of BH4 to iron in the complex FeH(dmpe)2(BH4)[dmpe = 1,2-bis(dimethylphosphino)ethane] is the first reported occurrence of that type of co-ordination of borohydride to iron; a detailed n.m.r. study has demonstrated the facile exchange of the bridging and termibal hydrogen atoms attached to the boron atom.Keywords
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