Protonation of some polynuclear carbonyl complexes
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 711-714
- https://doi.org/10.1039/j19700000711
Abstract
The protonation of some polynuclear carbonyl complexes in concentrated sulphuric acid has been studied and the new complexes [HRu3(CO)12]PF6 and [HOs3(CO)12]PF6 have been isolated. The kinetic isotope effect observed in these protonation reactions has been investigated and the new complex HOsCo3(CO)12 has been prepared.Keywords
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