Dynamic porous properties of coordination polymers inspired by hydrogen bonds
Top Cited Papers
- 4 January 2005
- journal article
- review article
- Published by Royal Society of Chemistry (RSC) in Chemical Society Reviews
- Vol. 34 (2) , 109-119
- https://doi.org/10.1039/b313997m
Abstract
In a decade, many porous coordination polymers have been synthesized, providing a variety of properties ranging from storage, separation, exchange of guests in their cavities, magnetism, conductivity and catalysis by their frameworks. In this tutorial review, we focus on the hydrogen bonding type arrangements for dynamic porous coordination polymers exhibiting elastic guest accommodations, in contrast to rigid three-dimensional (3-D) frameworks. Such dynamic porous properties induce highly-selective guest accommodation and magnetic modulation, and could now be considered a new class of practical materials.Keywords
This publication has 45 references indexed in Scilit:
- Crystal-to-Crystal Sliding of 2D Coordination Layers Triggered by Guest ExchangeAngewandte Chemie International Edition in English, 2002
- Novel Flexible Frameworks of Porous Cobalt(II) Coordination Polymers That Show Selective Guest Adsorption Based on the Switching of Hydrogen-Bond Pairs of Amide GroupsChemistry – A European Journal, 2002
- The Hydrogen Bond in the Solid StateAngewandte Chemie International Edition in English, 2002
- A Pillared-Layer Coordination Polymer Network Displaying Hysteretic Sorption: [Cu2(pzdc)2(dpyg)]n (pzdc= Pyrazine-2,3-dicarboxylate; dpyg=1,2-Di(4-pyridyl)glycol)Angewandte Chemie International Edition in English, 2002
- Highly Selective Guest Uptake in a Silver Sulfonate Network Imparted by a Tetragonal to Triclinic Shift in the Solid StateChemistry – A European Journal, 2001
- Solid-State Transformations of Zinc 1,4-Benzenedicarboxylates Mediated by Hydrogen-Bond-Forming MoleculesChemistry – A European Journal, 2001
- A New, Methane Adsorbent, Porous Coordination Polymer [{CuSiF6(4,4′-bipyridine)2}n]Angewandte Chemie International Edition in English, 2000
- Polymeric Layers Catenated by Ribbons of Rings in a Three-Dimensional Self-Assembled Architecture: A Nanoporous Network with Spongelike BehaviorAngewandte Chemie International Edition in English, 2000
- Three‐Dimensional Framework with Channeling Cavities for Small Molecules: {[M2(4, 4′‐bpy)3(NO3)4]·xH2O}n (M Co, Ni, Zn)Angewandte Chemie International Edition in English, 1997
- Supramolecular Synthons in Crystal Engineering—A New Organic SynthesisAngewandte Chemie International Edition in English, 1995