Facile C–H activation by lutetium–methyl and lutetium–hydride complexes
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 276-277
- https://doi.org/10.1039/c39830000276
Abstract
Bis(pentamethylcyclopentadienyl)lutetium complexes Lu(η5-C5Me5)2R (R = Me, H) react at 20–50 °C in hydrocarbon solvents with benzene, pyridine, the ylide CH2PPh3, and tetramethylsilane to give stable, isolatable products of C–H activation, i.e. metallation at a carbon of the reagent with extrusion of R–H.Keywords
This publication has 0 references indexed in Scilit: