Asymmetric Photochemistry and Photochirogenesis
- 30 August 2002
- journal article
- review article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 41 (17) , 3147-3154
- https://doi.org/10.1002/1521-3773(20020902)41:17<3147::aid-anie3147>3.0.co;2-v
Abstract
One of the most interesting phenomena on Earth is the chirality of biomolecules, the origin of which remains unknown. A challenge arising from this phenomenon is the selective, atom‐economic synthesis of enantiomerically pure target molecules from nonchiral starting materials. Herein, new developments in the field of asymmetric photochemistry and photochirogenesis are described with special emphasis on absolute asymmetric synthesis. In this context, the elucidation of the ultimate cause of homochirality phenomena on earth and the possible correlation with physicochemical parameters are also presented.Keywords
This publication has 85 references indexed in Scilit:
- Unidirectional Photoinduced Shuttling in a Rotaxane with a Symmetric Stilbene DumbbellAngewandte Chemie, 2002
- Intermolecular hydrogen binding of a chiral host and a prochiral imidazolidinone: enantioselective Norrish–Yang cyclisation in solutionChemical Communications, 2001
- The origin and amplification of biomolecular chiralityDiscover Life, 1991
- Possible amplification of enantiomer excesses through structural properties of liquid crystals — A model for origin of optical activity in the biosphere?Discover Life, 1990
- Effects of electric and magnetic fields on prochiral chemical reactions: macroscopic electric and magnetic fields can cause asymmetric synthesisJournal of the American Chemical Society, 1978
- Synthesis of Cystine in Simulated Primitive ConditionsNature, 1971
- Photochemistry with circularly polarized light. Synthesis of optically active hexaheliceneJournal of the American Chemical Society, 1971
- Distribution of Pethidine and Chlorpromazine in Maternal, Foetal and Neonatal Biological FluidsNature, 1971
- A hypothesis for the asymmetric appearance of biomolecules on earthJournal of Theoretical Biology, 1966
- On spontaneous asymmetric synthesisBiochimica et Biophysica Acta, 1953