Electrospray mass spectrometry evidence for an oxo-manganese(V) species generated during the reaction of manganese triazacyclononane complexes with H2O2 and 4-methoxyphenol in aqueous solution

1 January 1998

journal article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2

No. 9,p. 1841-1844
https://doi.org/10.1039/a804884c

Abstract

Electrospray mass spectrometry has been used to identify the formation of oxo-manganese(V) species in the oxidation of 4-methoxyphenol by H₂O₂ catalysed by manganese 1,4,7-triazacyclononane complexes in aqueous solution.

Keywords

MASS SPECTROMETRY
OXO
H2O2 CATALYSED
SPECIES GENERATED
SOLUTION ELECTROSPRAY
MANGANESE TRIAZACYCLONONANE
SPECTROMETRY EVIDENCE

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