Enhancing Effect of Titanium(II) for the Oxidation of Methane with O2 by an EuCl3-Zn-CF3CO2H-Catalytic System at 40 °C
- 1 July 1996
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 25 (7) , 565-566
- https://doi.org/10.1246/cl.1996.565
Abstract
Bis(2,4,-pentanedionate)TiO and TiO2 enhanced markedly the activity of the EuCl3-Zn0-CF3CO2H-catalytic system for the CH4 oxidation to MeOH with O2 at 40 °C. It is suggested that Ti(II) species generated from Ti(IV) by the reduction with Zn0 and CF3CO2H is responsible for this enhancement.This publication has 2 references indexed in Scilit:
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- Formation and dissociation kinetics of nickel(II) with ionophore A23187 in 80% methanol-waterJournal of the American Chemical Society, 1987