Conformational analysis of apparicine using 1H nuclear magnetic relaxation: application of transient nuclear Overhauser enhancements
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 6,p. 919-924
- https://doi.org/10.1039/p29800000919
Abstract
1 H N.m.r. relaxation in apparicine in [2H6]acetone solution has been studied. Spin–lattice relaxation times, and selected steady-state and transient nuclear Overhauser enhancements are reported. In conjunction with spin–spin coupling constants these results permit an assignment of the molecular conformation.Keywords
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