Solvent-free synthesis of clathrasils using metal–organic complexes as structure-directing agents
- 1 January 1995
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 2559-2561
- https://doi.org/10.1039/c39950002559
Abstract
The two metal–organic complex salts [Co(C5H4Me)2]PF6 and [Fe(C6H6)(C5H5)]PF6 are tested as structure-directing agents in the synthesis of pure silica zeotype materials and give the clathrasil structure dodecasil-1H only in the suivent free synthesis system SiO2–NH4F–metal complex.Keywords
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