Pyrolysis of Polymer Complexes Leading to Air-Stable Ultrafine Metal Particles Uniformly Dispersedin a Carbon Matrix
- 1 August 1990
- journal article
- research article
- Published by Taylor & Francis in Journal of Macromolecular Science: Part A - Chemistry
- Vol. 27 (9-11) , 1347-1361
- https://doi.org/10.1080/00222339009349696
Abstract
New types of air-stable metal-carbon composites which contain ultrafine metal particles (Fe, Co, Ni, Pd, Pt, Rh, Cu, etc.) uniformly dispersed in a carbon matrix were obtained by pyrolysis of a variety of soluble organometallic polymers, macromolecular-metal complexes, and blends of coal pitch with metal complexes at 400-1400°C in N2. Some of their unique physical properties and functions are noted.Keywords
This publication has 16 references indexed in Scilit:
- Synthesis of iron-dispersed carbons by pressure pyrolysis of divinylbenzene-vinylferrocene copolymerJournal of Materials Science, 1983
- Dispersion of iron phthalocyanine on carbon surfacesJournal of Colloid and Interface Science, 1983
- Intercalation compounds of graphiteAdvances in Physics, 1981
- High-temperature compatibility of carbon fibres with nickelJournal of Materials Science, 1978
- Bromination and lithiation: two important steps in the functionalization of polystyrene resinsThe Journal of Organic Chemistry, 1976
- MÖSSBAUER MEASUREMENTS OF IRON ATOMS DISPERSED IN AMORPHOUS GLASSLIKE CARBONSChemistry Letters, 1974
- Organometallic Polymers. XXVII. Radical-Initiated Polymerization and Copolymerization of π-(2, 4-Hexadien-1-yl Acrylate) tricarbonylironJournal of Macromolecular Science: Part A - Chemistry, 1973
- Formation of filamentous carbon from iron, cobalt and chromium catalyzed decomposition of acetyleneJournal of Catalysis, 1973
- Catalytic reduction of olefins with a polymer-supported rhodium(I) catalystJournal of the American Chemical Society, 1971
- 868. Cobalt(II) complexes of 2- and 4-vinylpyridinesJournal of the Chemical Society, 1965