Organosilyl iron carbonyl complexes: synthesis and reactivity towards alkynes and nitriles
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 278-279
- https://doi.org/10.1039/c39800000278
Abstract
The di-iron complex [Fe(CO)4SiPh2]2, readily obtained from Fe(CO)5 and Ph2SiH2 under photochemical conditions, reacts with the alkynes RCCR to yield the new mono- and bi-metallic complexes (CO)4[graphic omitted]iPh2(R = Ph, Me, or Et) and (CO)3[graphic omitted](CO)3; the former complexes convert nitriles into aldehydes via disilylated enamines.Keywords
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