Erste Kristallstrukturanalyse eines aliphatischen Carbokations – Stabilisierung des 3,5,7‐Trimethyl‐1‐adamantyl‐Kations durch C‐C‐Hyperkonjugation
- 1 April 1986
- journal article
- zuschrift
- Published by Wiley in Angewandte Chemie
- Vol. 98 (4) , 368-369
- https://doi.org/10.1002/ange.19860980430
Abstract
No abstract availableKeywords
This publication has 13 references indexed in Scilit:
- Relative reactivity of bridgehead adamantyl and homoadamantyl substrates from solvolyses with heptafluorobutyrate as a highly reactive carboxylate leaving group. Absence of SN2 character of solvolysis of tert-butyl derivativesJournal of the American Chemical Society, 1985
- Coordination of a "noncoordinating" anion: x-ray crystal structure and phosphorus-31 NMR characterization of a tungsten nitrosyl cation ligated to hexafluoroantimonate(1-) ionJournal of the American Chemical Society, 1985
- Bridgehead adamantyl, diamantyl, and related cations and dicationsJournal of the American Chemical Society, 1985
- Polar Effects. X. Polar Substituent Effects in the Solvolysis of 3‐Substituted 1‐Adamantyl Bromides and ToluenesulfonatesHelvetica Chimica Acta, 1982
- Hyperconjugation and homohyperconjugation in the 1-adamantyl cation. Qualitative models for .gamma.-deuterium isotope effectsJournal of the American Chemical Society, 1979
- Inductive, Hyperconjugative and Frangomeric Effects in the Solvolysis of 1‐Substituted 3‐Bromoadamantanes. Polar effects IVHelvetica Chimica Acta, 1978
- Crystal structure, Raman spectrum, and nuclear magnetic resonance spectrum of methoxythionyl .mu.-fluoro-bis(pentafluoroantimonate(V)), CH3OSO+Sb2F11-Journal of the American Chemical Society, 1976
- Preparative Carbocation Chemistry; VII1. Isolation of Alkyl(cycloalkyl)carbenium Ion Salts: Trimethylcarbenium (t-Butyl), Tricyclopropylcarbenium, and 1-Adamantyl Fluoroantimonates.Synthesis, 1973
- The Proton Magnetic Resonance Spectra of Adamantane and Its Derivatives1The Journal of Organic Chemistry, 1965
- Über Verbindungen mit Urotropin‐Struktur, XII. Monofunktionelle Adamantan‐DerivateEuropean Journal of Inorganic Chemistry, 1959