Fluorination of tetrairidium dodecacarbonyl
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1577-1578
- https://doi.org/10.1039/c39920001577
Abstract
Xenon difluoride sequentially fluorinates Ir4(CO)12 dissolved in anhydrous HF yielding initially the novel neutral complexes mer- and fac-Ir(CO)3F3, which are characterised by 19F, 13C and 13C{19F} NMR spectroscopies, and finally [XeF][IrF6].Keywords
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