New Terpenic Synthons: Methyl α- and γ-Dithiocyclogeranates
- 1 January 1987
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1987 (03) , 267-270
- https://doi.org/10.1055/s-1987-27911
Abstract
Methyl γ-dithiocyclogeranate, a new terpenic dithioester. was easily synthesized by the [2,3]-sigmatropic rearrangement of tosylhydrazone derivative 6a. Treatment with acid gives methyl α-dithiocyclogeranate. Three methoxylated analogues are obtained in the same way.Keywords
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