Disproportionation of sulfur dioxide to octasulfur and sulfur trioxide on Cp*2Cr2S5. Crystallographic and sulfur-34-labeling evidence for an oxygen-transfer mechanism and observation of facile exchange of Cr2S5 core sulfurs with 34S. Structures of Cp*2Cr2(.mu.-S)(.mu.-.eta.2-S2)(.mu.-.eta.1-SS.cntdot.SO2).cntdot.SO2 and Cp*2Cr2(.mu.-S)(.mu.-.eta.2-S2)(.mu.-SSO3)
- 1 September 1992
- journal article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 31 (18) , 3810-3817
- https://doi.org/10.1021/ic00044a025
Abstract
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