Facile thermally-induced cluster oxidations in metallaborane chemistry: arachno→nido→closo reaction sequences exhibited by iridanonaboranes and iridadecaboranes, and the stabilization of the iridium(V) oxidation state
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 346-348
- https://doi.org/10.1039/c39820000346
Abstract
Iridanonaboranes and iridadecaboranes which have adjacent open-face bridging H atoms and terminal Ir–H atoms readily lose H2 in formal cluster oxidations which involve stable isolable iridium (V) species.Keywords
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