Studies on the Metabolic Products of a Strain of Aspergillus fumigatus (DH 413).III.Biosynthesis of Toluquinones

Abstract
The relationship among the metabolites of Aspergillus fumigatus DH 413 was studied by using 14c-labelled compounds 14c-Labelled 2-methyl-5-methoxy-6-hydroxy-2,3-epoxy-p-benzoquinone was well incorporated into fumigatin and fumi-gatin quinol, but the reverse reaction was not observed, and it is suggested that the epoxydation step is involved in the biosynthesis of toluquinones.

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