Synthesis and Reactivity of a Mono-σ-Aryl Palladium(IV) Fluoride Complex
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- 27 February 2009
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 131 (11) , 3796-3797
- https://doi.org/10.1021/ja8054595
Abstract
This communication describes the rational design and synthesis of the remarkably stable PdIV monoaryl fluoride complex (t-Bu-bpy)PdIV(p-FC6H4)(F)2(FHF) (t-Bu-bpy = 4,4′-di-tert-butyl-2,2′-bipyridine). This and related complexes undergo Ar−F bond formation in the presence of “F+” sources. This work serves as a foundation for the development of PdII/IV-catalyzed coupling reactions to form aryl fluorides.Keywords
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