Complexes containing cobalt–silicon metal–metal bonds
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 11,p. 524-525
- https://doi.org/10.1039/c29710000524
Abstract
The complexes (Ph3P)3CoH2(SiR3)(R F, OEt) are formed by an oxidative-elimination reaction between R3SiH and (Ph3P)3Co(N2)H; the reaction is reversible when R OEt, and this complex function as an efficient catalyst for O-silylation and hydrosilylation reactions.Keywords
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