Higher valent manganese chemistry. [Mn(biguanide)3]+, a structurally characterized Mn IV complex with all-nitrogen coordination

Abstract
Oxidation of MnII acetate with Bun 4NMnO4 in the presence of biguanide (big H) affords the red [MnIV(big)3]+ cation, a rare non-porphyrinic example of a MnIV complex coordinated solely through N atoms.
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