Ideal gas thermodynamic properties of six chlorofluoromethanes

Abstract
Spectroscopic and thermal data were reviewed. The selected values for the principal moments of inertia, the vibrational fundamentals, and the standard enthalpy of formation at 298.15 K for each of the six chlorofluoromethanes were used to derive the chemical thermodynamic properties of molecules from 0 to 1500 K, based on the rigid-rotor harmonic-oscillator approximation. The calculated values are in accord with experimental heat capacities and entropies.