1-Chloro and 1-Hydroxyphospholene-1-oxides
- 1 January 1975
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 5 (1) , 45-58
- https://doi.org/10.1080/00945717508057297
Abstract
A one-step, high-yield procedure is reported for the preparation of a 1:1 mixture of the two isomers of 1-chlorophospholene-1-oxide which may be separated by spinning band distillation. The isomerically pure chlorides were hydrolyzed to form the corresponding 1-hydroxyphospholene-1-oxides. These, as well as the precursor chlorides, were characterized by 1H and 31P nmr, mass spectrometry and IR.Keywords
This publication has 6 references indexed in Scilit:
- Phospholene SulfidesSynthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 1974
- Katalytische reaktionen von 1-oxo-1-alkoxyphospholinenTetrahedron Letters, 1966
- Phospholin-derivate, III Die Reaktion von 1,1,1-Trichlorphospholinen mit Orthocarbonyl-VerbindungenTetrahedron Letters, 1964
- Spektroskopische Bestimmung der Doppelbindungslage in PhospholinenAnalytical and Bioanalytical Chemistry, 1964
- Phospholin-derivate—IITetrahedron, 1964
- Phospholin-derivate aus phosphor-trihalogeniden und dienenTetrahedron, 1963