The phase transformations in Pb5Ge3O11 and in the Pb5Ge3-xSixO11 mixed crystals system

Abstract
Measurements of FIR transmission of Pb3Ge3O11 at 20. 2 cm-1 using a FIR laser are presented. Moreover, evidence for further phase transitions above Tc = 450 K are discussed.Improved lattice constants of Pb5Ge3-xSixO11 mixed crystals show a remarkable negative deviation from Vegard's rule corresponding with the respective change of Tc.

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