Synthesis of polymer-encapsulated mono- and bi-nuclear metal isocyanide complexes
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 211-213
- https://doi.org/10.1039/c39860000211
Abstract
Matrix-scale metal vapour reactions of Fe and Ni with an isocyano-functionalised polysiloxane (1) afford novel polymer-encapsulated mononuclear metal isocyanide complexes [M(CNR)n; M = Fe, n= 5; M = Ni, n= 4], which in the case of Fe can be photolysed to give the binuclear Fe2(CNR)9 species, while Co vapour yeilds the Co2(CNR)8 species directly; the results of preparative scale reactions with Co and Ni are in good agreement with these studies.Keywords
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