Formation and destruction of the guanine quartet in solution observed by cold-spray ionization mass spectrometryElectronic supplementary information available: CSI and ESI mass spectra of dG, dC, dA and dT, and schematic diagram of the coldspray ion source. See http://www.rsc.org/suppdata/cc/b2/b212432g/

Abstract
The dynamic solution behavior during formation of the 2′-deoxyguanosine tetrad (G-quartet) upon addition of alkali metal cations and destruction of the G-quartet upon addition of the guanine–guanine mismatch recognition molecule naphthyridine dimer was observed by cold-spray ionization mass spectrometry.

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