The dielectric constant of a bonded lattice model for water
- 1 December 1977
- journal article
- Published by IOP Publishing in Journal of Physics A: General Physics
- Vol. 10 (12) , 2153-2169
- https://doi.org/10.1088/0305-4470/10/12/023
Abstract
The formula for the dielectric constant of a liquid, derived by Onsager, is modified to take account of the effect, on molecular orientations in water, of hydrogen bonding. This is achieved by using the lattice model of Bell. By a suitable choice of parameters, isobars are obtained for the dielectric constant as a function of temperature. These are in fair agreement with experiment and illustrate well the important role of hydrogen bonding.Keywords
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