Semiconducting polymers based on charge‐transfer complexes. I. Synthesis of electron‐donor‐containing poly‐N‐acylethylnimines
- 1 June 1973
- journal article
- research article
- Published by Wiley in Journal of Polymer Science: Polymer Chemistry Edition
- Vol. 11 (6) , 1339-1351
- https://doi.org/10.1002/pol.1973.170110620
Abstract
Polymers were made which contained 10‐methyl, 3‐phenothiazinyl, and 4‐(methylthio)phenoxy electron‐donating groups on side chains. N‐Acyl‐substituted poly‐ethylenimines were chosen because the repeat distance along the polymer chain is the same as the repeat distance in most aromatic charge‐transfer complexes (about 6.4 Å) and the side chains do not interfere with each other. This paper describes synthetic routes for preparation of these electron‐donor‐containing polymers. Synthesis of a polyacrylate donor is also described.Keywords
This publication has 18 references indexed in Scilit:
- Semiconducting polymers based on charge‐transfer complexes. III. Complexing and chemical stability of charge‐transfer complexes in solutionJournal of Polymer Science: Polymer Chemistry Edition, 1973
- Recent Syntheses and Reactions of Cyclic Imidic EstersAngewandte Chemie International Edition in English, 1966
- Substituted Quinodimethans. II. Anion-radical Derivatives and Complexes of 7,7,8,8-TetracyanoquinodimethanJournal of the American Chemical Society, 1962
- Organic Chemistry of Ferrocene. II. The Preparation of Ferrocenyl AliphaticJournal of the American Chemical Society, 1957
- Synthesis of Alkyl and Substituted Alkyl Fluorides from p-Toluenesulfonic Acid Esters. The Preparation of p-Toluenesulfonic Acid Esters of Lower Alcohols1Journal of the American Chemical Society, 1955
- Oxidation of 10-Acyl- and 10-AlkylphenothiazinesJournal of the American Chemical Society, 1953
- Some 10-Substituted PhenothiazinesJournal of the American Chemical Society, 1952
- A Simple Modification of the Wolff-Kishner ReductionJournal of the American Chemical Society, 1946
- The Mechanism of the Aqueous Hydrolysis of β-ButyrolactoneJournal of the American Chemical Society, 1938
- The Synthesis of ▵2-Oxazolines and ▵2-Thiazolines from N-Acyl-2-aminoethanolsJournal of the American Chemical Society, 1935